Abstract

Two ratiometric thermometry methods based on the interplay between Eu2+ and Eu3+ and single Eu3+ emissions on OH-free low-silica calcium aluminosilicate glass.
ZANUTO, Vitor Santaella; CAPELOTO, O. A.; MUNIZ, R. F.; SANDRINI, M.; ROHLING, J. H.; BAESSO, M. L.; NUNES, Luiz Antônio de Oliveira.
Abstract: The constant demand to accurately measure the temperature sheds light on luminescent materials that have dependence on their thermodynamic quantities. Several materials have been applied as sensors to measure temperature for different applications, however, very few showed high precision and sensitivity. This work reports the Eu/Eu-doped low-silica calcium aluminosilicate glass as a potential candidate for high sensitive ratiometric thermometer. The glass was analyzed close to the physiological temperature range, between 288.15 - 333.15 K. Since this glassy matrix provides the presence of two europium valences, two different approaches are presented. The first takes into account the temperature dependence of 5D0 ? 7F4 emission for two different excitation wavelengths, and the second one is based on the interplay between Eu and Eu emissions. Both ratiometric approaches presented high reproducibility and relative sensitivity values, from 1.2 to 1.6 %/K and from 0.75 to 0.95 %/K, for the first and second approach, respectively.
Materials Research Bulletin
v. 135, p. 111115-1-111115-6 - Ano: 2021
Fator de Impacto: 4,019
    @article={003014012,author = {ZANUTO, Vitor Santaella; CAPELOTO, O. A.; MUNIZ, R. F.; SANDRINI, M.; ROHLING, J. H.; BAESSO, M. L.; NUNES, Luiz Antônio de Oliveira.},title={Two ratiometric thermometry methods based on the interplay between Eu2+ and Eu3+ and single Eu3+ emissions on OH-free low-silica calcium aluminosilicate glass},journal={Materials Research Bulletin},note={v. 135, p. 111115-1-111115-6},year={2021}}

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